Technology of Fluoropolymers - Jiri G. Drobny

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Résumé :

PART I OVERVIEW OF FLUOROPOLYMERS

1 Introduction

2 Societal Benefits and Evolution of Fluoropolymers 2.1 Basic Fluoropolymer Properties 2.2 Examples of Fluoropolymer Properties 2.3 Automotive Applications 2.4 Aerospace Wire and Cable 2.5 Aircraft Fuel Hose 2.6 Heart Rhythm Management-ICD 2.7 Pediatric Heart Repair 2.8 Thread Sealant 2.9 Chemical Processing Industry-Lined Pipes, Fittings, and Vessels 2.10 Semiconductor Chip Fabrication 2.11 Biomedical Applications 2.12 PTFE Micropowders 2.13 Applications of Fluoropolymers in Transportation 2.14 Properties of Thermoplastic Fluoropolymers 2.15 Delving Deeper into Properties 2.16 Forces Affecting the Fluoropolymer Industries References

PART II THERMOPLASTIC FLUOROPOLYMERS

3 Synthesis and Properties of Monomers of Thermoplastic Fluoropolymers 3.1 Preparation of Tetrafluoroethylene 3.2 Properties of Tetrafluoroethylene 3.3 Preparation of Hexafluoropropylene 3.4 Properties of Hexafluoropropylene 3.5 Synthesis of Perfluoroalkylvinylethers (PAVEs) 3.6 Properties of Perfluoroalkylvinylethers 3.7 Synthesis of Chlorotrifluoroethylene (CTFE) 3.8 Properties of Chlorotrifluoroethylene 3.9 Synthesis of Vinylidene Fluoride (VDF) 3.10 Properties of Vinylidene Fluoride 3.11 Synthesis of Vinyl Fluoride (VF) 3.12 Properties of Vinyl Fluoride (VF) References

4 Polymerization of Commercial Thermoplastic Fluoropolymers 4.1 Polymerization of Tetrafluoroethylene 4.1.1 Granular Resins 4.1.2 Fine Powder Resins 4.1.3 Aqueous Dispersions 4.1.4 Filled Compounds 4.1.5 Modified PTFE 4.2 Fluorinated Ethylene Propylene (FEP) 4.2.1 Industrial Process for the Production of FEP 4.3 Perfluoroalkoxy (PFA) Resin 4.3.1 Industrial Process for the Production of Perfluoroalkoxy Resin 4.4 Polychlorotrifluoroethylene (PCTFE) 4.4.1 Industrial Process for the Production of PCTFE 4.5 Polyvinylidene Fluoride (PVDF) 4.5.1 Industrial Process for the Production of PVDF 4.6 Polyvinyl Fluoride 4.6.1 Industrial Process for the Production of Polyvinyl Fluoride 4.7 Ethylene Chlorotrifluoroethylene (ECTFE) Copolymer 4.7.1 Industrial Process for the Production of ECTFE 4.8 Ethylene Tetrafluoroethylene (ETFE) Copolymer 4.8.1 Industrial Process for the Production of ETFE 4.9 Terpolymers of TFE, HFP and VDF (THV Fluoroplastic) 4.10 Terpolymers and Quarterpolymers of HFP, TFE and Ethylene References

5 Properties of Commercial Fluoropolymers 5.1 Properties as Related to the Structure of Fluoropolymers 5.1.1 Fluoroplastics 5.1.1.1 Mechanical Properties 5.1.1.2 Optical Properties 5.1.2 Fluoroelastomers 5.2 Properties of Individual Commercial Fluoroplastics 5.2.1 Polytetrafluoroethylene 5.2.1.1 Molecular Weight 5.2.1.2 Molecular Conformation 5.2.1.3 Crystallinity and Melting Behavior 5.2.1.4 Mechanical Properties 5.2.1.5 Surface Properties 5.2.1.6 Absorption and Permeation 5.2.1.7 Electrical Properties 5.2.2 Modified Polytetrafluoroethylene 5.2.3 Copolymers of Tetrafluoroethylene and Hexafluoropropylene (FEP) 5.2.3.1 Mechanical Properties 5.2.3.2 Electrical Properties 5.2.3.3 Chemical Properties 5.2.3.4 Optical Properties 5.2.3.5 Other Properties 5.2.4 Copolymers of Tetrafluoroethylene and Perfluoroalkyl Ethers (PFA and MFA) 5.2.4.1 Physical and Mechanical Properties 5.2.4.2 Electrical Properties 5.2.4.3 Optical properties 5.2.4.4 Chemical Properties 5.2.5 Copolymers of Ethylene and Tetrafluoroethylene (ETFE) 5.2.5.1 Structure and Related Properties 5.2.5.2 Mechanical, Chemical and Other Properties 5.2.6 Polyvinylidene Fluoride (PVDF) 5.2.6.1 Mechanical Properties 5.2.6.2 Electrical Properties 5.2.6.3 Chemical Properties 5.2.7 Polychlorotrifluoroethylene (PCTFE) 5.2.7.1 Thermal Properties 5.2.7.2 Mechanical, Chemical and Other Properties 5.2.8. Copolymer of Ethylene and Chlorotrifluoroethyl...

Biographie:

Mr. Jiri George Drobny

Jiri George Drobny is the President of Drobny Polymer Associates, an international consulting firm specializing in fluoropolymer science and technology, radiation processing and elastomer technology. His career spans over 50 years in the polymer processing industry in Europe, the US and Canada, mainly in R&D with senior and executive responsibilities. Mr. Drobny is also active as an educator, author, and as technical and scientific translator. He is member of the Society of Plastic Engineers, American Chemical Society, Rubber Division of ACS and RadTech International. He resides in New Hampshire.

Dr Sina Ebnesajjad

Sina Ebnesajjad is the founder of FluoroConsultants Group (FCG) and has been the President of the company since 2006. He retired as a Sr Technology Associate in 2005 from the DuPont Co. after 23 years. FCG serves companies in a variety of areas including consulting, custom manufacturing and sourcing fluoropolymers. He is author, co-author and editor of over a dozen technical books including seven on fluoropolymers and three on the surface treatment of materials and adhesives technology.