Nitrogen-Rich Energetic Materials - Michael Gozin

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Résumé :

Preface xi

About the Editors xv

1 Chemistry of Pentazole 1
Ming Lu, Pengcheng Wang, Yuangang Xu, and Qiuhan Lin

1.1 Introduction 1

1.2 Substituted Pentazoles 1

1.3 Strategies for the Preparation of cyclo-N5- 5

1.4 Complexes of Metal and cyclo-N5- 9

1.5 cyclo-N5--Based Nonmetallic Ionic Salts 25

1.6 Conclusions 43

2 Aromatic Fused-Ring-Based Energetic Compounds 47
Kangcai Wang and Qinghua Zhang

2.1 Introduction 47

2.2 Fused-Ring Aromatic Energetic Compounds 49

2.3 Conclusions 68

3 Advances in Computations of Nitrogen-Rich Materials 73
Lei Zhang and Chuang Yao

3.1 Why Computation and What Role It Plays? 73

3.2 Why Nitrogen-Rich HEDMs and How TheyWork? 74

3.3 Advances in Computation of First-Generation Nitrogen-Rich HEDMs 75

3.4 Advances in Computation of Second-Generation Nitrogen-Rich HEDMs 81

3.5 Advances in Computation of Third-Generation Nitrogen-Rich HEDMs: Polynitrogen Materials 84

3.6 Final Remarks 97

Acknowledgement 98

References 98

4 Laser Ignition of Energetic Transition Metal Complexes 107
Maximilian Wurzenberger, Daniel Shem-Tov, and J?rg Stierstorfer

4.1 Introduction 107

4.2 Synthesis of Energetic Coordination Compounds 116

4.3 Synthesis of Energetic Tetrazole Ligands 116

4.4 Synthesis Energetic Coordination Complexes 121

4.5 Examples of Molecular Structures 122

4.6 Energetic Properties of Ligands and Corresponding Energetic Coordination Compounds 122

4.7 UV-Vis Spectroscopy of Energetic Coordination Compounds 128

4.8 Studies of Ignition Mechanism 128

4.9 Conclusions 134

5 Energetic 1,2,3,4-Tetrazines 139
Aleksandr M. Churakov, Michael S. Klenov, Aleksey A. Voronin, and Vladimir A. Tartakovsky

5.1 Introduction 139

5.2 Methods of Synthesis and Reactivity of 1,2,3,4-Tetrazines 141

5.3 NMR and X-ray Studies 164

5.4 Thermal Stability 168

5.5 Applications 177

References 179

6 Recent Advances in Chemistry of Nitrogen-Rich Energetic Polymers and Plasticizers 189
Michael Gozin and Leonid L. Fershtat

6.1 Introduction 189

6.2 Heterocyclic Energetic Polymers and Plasticizers 189

6.3 Nitrogen-Rich Energetic Polymers Lacking Traditional Explosophoric Groups 201

6.4 Azido-Rich Energetic Polymers and Plasticizers 202

6.5 Azido Fluoropolymers 216

6.6 Azido Plasticizers 219

6.7 Nitro Group Containing Polymers 225

6.8 Aromatic C-NO2 Containing Polymers 230

6.9 Conclusions 234

References 234

7 Tetrazole Energetic Salts Based on Various Explosophores: Recent Overview of Synthesis and Energetic Properties 239
Saira Manzoor, Qamar-un-nisa Tariq, and Jian-Guo Zhang

7.1 Introduction 239

7.2 Tetrazole-Based Energetic Salts 241

7.3 Conclusion and Future Trends 278

7.4 Cautions 280

Acknowledgments 280

References 280

8 Properties and Application of Nitrogen-Rich Compound BTATz in Low-Signature Propellants 285
Jianhua Yi, Zhihua Sun, Yi Xu, Zhao Qin, Changjian Wang, Bozhou Wang, Hui Li, Haijian Li, Chao Chen, Xiao Xie, and Fengqi Zhao

8.1 Introduction 285

8.2 Synthesis of BTATz 286

8.3 Structure of BTATz 287

8.4 Properties of BTATz 290

8.5 Energetic Properties of the Propellants 291

8.6 Plume Smoke Signature of the Propellants 295

8.7 Preparation of the Propellants 296

8.8 Decomposition Reaction Kinetics and Thermal Safety of the Propellants 297

8.9 C...

Biographie:
Prof. Michael Gozin is a Faculty Member of the School of Chemistry (Faculty of Exact Sciences) at the Tel Aviv University (TAU) in Tel Aviv, Israel. He has B.Sc. degree in chemistry from the Hebrew University (Jerusalem) and M.Sc. and Ph.D. degrees in Organic Chemistry from the Weizmann Institute of Science (Rehovot, Israel). Prior joining the TAU, Prof. Gozin had several industrial positions in PeproTech (NJ, US) and Clinical Microsensors (CA, US). He was also a Chairman of the National Committee in Chemistry and Materials of the Israeli National Institute of Standards. Prof. Gozin has authored over 90 scientific publications, 19 patents and patent applications, a book chapter. Prof. Gozin is an Editor-in-Chief of the Energetic Materials Frontiers journal and an Editorial Board member of Defence Technology journal.
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Sommaire:
1 Chemistry of Pentazole
2 Aromatic Fused-Ring Based Energetic Compounds
3 Advances in Computations of Nitrogen-Rich Materials
4 Laser Ignition of Energetic Transition Metal Complexes
5 Energetic 1,2,3,4-Tetrazines
6 Recent Advances in Chemistry of Nitrogen-Rich Energetic Polymers and Plasticizers
7 Tetrazole Energetic Salts Based on Various Explosophores: Recent Overview of Synthesis and Energetic Properties
8 Properties and Application of Nitrogen-Rich Compound BTATz in Low-Signature Propellants
9 Nitro-substituted Oxadiazoles: Important Building Blocks in the Synthesis of Energetic Compounds
10 Insensitive High Explosives Containing Tetraazapentalene Moiety
11 Nitrogen-rich Pyrotechnic Materials for Light and Smoke
...