Solid State Chemistry and Its Applications - Anthony R West

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Auteur(s) : Anthony R West

Editeur : Wiley

Langue : Anglais

Parution : 01/05/2022

Format : Moyen, de 350g à 1kg

Nombre de pages : 896

Expédition : 1976

Dimensions : 26.0 x 18.5 x 4.2

ISBN : 9781118447444

Résumé :

SOLID STATE CHEMISTRY AND ITS APPLICATIONS

A comprehensive treatment of solid state chemistry complete with supplementary material and full colour illustrations from a leading expert in the field.

Solid State Chemistry and its Applications, Second Edition delivers an advanced version of West's classic text in solid state chemistry, expanding on the undergraduate Student Edition to present a comprehensive treatment of solid state chemistry suitable for advanced students and researchers. The book provides the reader with an up-to-date account of essential topics in solid state chemistry and recent developments in this rapidly developing field of inorganic chemistry.

Significant updates and new content in this second edition include:

• A more extensive overview of important families of inorganic solids including spinels, perovskites, pyrochlores, garnets, Ruddlesden-Popper phases and many more
• New methods to synthesise inorganic solids, including sol-gel methods, combustion synthesis, atomic layer deposition, spray pyrolysis and microwave techniques
• Advances in electron microscopy, X-ray and electron spectroscopies
• New developments in electrical properties of materials, including high Tc superconductivity, lithium batteries, solid oxide fuel cells and smart windows
• Recent developments in optical properties, including fibre optics, solar cells and transparent conducting oxides
• Advances in magnetic properties including magnetoresistance and multiferroic materials
• Homogeneous and heterogeneous ceramics, characterization using impedance spectroscopy
• Thermoelectric materials, MXenes, low dimensional structures, memristors and many other functional materials
• Expanded coverage of glass, including metallic and fluoride glasses, cement and concrete, geopolymers, refractories and structural ceramics
• Overview of binary oxides of all the elements, their structures, properties and applications

Featuring full color illustrations throughout, readers will also benefit from online supplementary materials including access to CrystalMaker? software and over 100 interactive crystal structure models.

Perfect for advanced students seeking a detailed treatment of solid state chemistry, this new edition of Solid State Chemistry and its Applications will also earn a place as a desk reference in the libraries of experienced researchers in chemistry, crystallography, physics, and materials science.

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Biographie:
The Parallel RC Element 621

11.3 Impedance Formalisms, Alternating Currents and Equivalent Circuits 624

11.4 Applications of Impedance Spectroscopy 634

12 Thermal and Thermoelectric Properties 647

12.1 Thermoelectric Effects 647

12.2 Thermal Properties: Heat Capacity, Thermal Conductivity, Thermal Expansion 656

13 Functional Materials: Some Important Examples 663

13.1 TiO2: Rutile, Anatase and Other Ti-O Phases 663

13.2 Ca12Al14O33, Mayenite: An Oxide Ion Conductor, Component of Cement and a uperconducting Electride 680

13.4 Two-dimensional Structures: MXenes 689

13.5 Low-dimensional Solids: Graphene, BN, Transition Metal Dichalcogenides and Black Phosphorus 692

14 Glass 697

14.1 Factors That Influence Glass Formation 698

14.2 Thermodynamics of Glass Formation...

Sommaire:

Preface xxi

Companion Website xxiii

Biography xxv

Solid State Chemistry, an Overview of the Discipline: Chemistry - Solid State

Chemistry - Materials Chemistry - Materials Science and Engineering 1

1 Crystal Structures, Crystal Chemistry, Symmetry and Space Groups 7

1.1 Unit Cells and Crystal Systems 7

1.2 Symmetry 9

1.3 Symmetry and Choice of Unit Cell 16

1.4 Lattice, Bravais Lattice 18

1.5 Lattice Planes and Miller Indices 20

1.6 Indices of Directions 22

1.7 d-Spacing Formulae 23

1.8 Crystal Densities and Unit Cell Contents 23

1.9 Description of Crystal Structures 24

1.10 Close Packed Structures - Cubic and Hexagonal Close Packing 25

1.11 Relationship Between Cubic Close Packed and Face Centred Cubic 27

1.12 Hexagonal Unit Cell and Close Packing 27

1.13 Density of Close Packed Structures 28

1.14 Unit Cell Projections and Atomic Coordinates 30

1.15 Materials that can be Described as Close Packed 31

1.16 Structures Built of Space-Filling Polyhedra 39

1.17 Some Important Structure Types 42

1.18 Point Groups and Space Groups 99

2 Crystal Defects, Non-stoichiometry and Solid Solutions 119

2.1 Perfect and Imperfect Crystals 119

2.2 Types of Defect: Point Defects 120

2.3 Solid Solutions of Ionic Materials 131

2.4 Extended Defects 143

2.5 Dislocations and Mechanical Properties of Solids 147

3 Bonding in Solids 161

3.1 Overview: Ionic, Covalent, Metallic, van der Waals and Hydrogen Bonding in Solids 161

3.2 Ionic Bonding 162

3.3 Covalent Bonding 196

3.4 Metallic Bonding and Band Theory 207

3.5 Bands or Bonds: A Final Comment 220

4 Synthesis, Processing and Fabrication Methods 221

4.1 General Observations 221

4.2 Solid State Reaction or Shake 'n Bake Methods 221

4.3 Low Temperature or Chimie Douce Methods 230

4.4 Gas-Phase Methods 247

4.5 High-Pressure Methods 258

4.6 Crystal Growth 261

5 Crystallography and Diffraction Techniques 265

5.1 General Comments: Molecular and Non-Molecular Solids 265

5.2 Characterisation of Solids 267

5.3 X-Ray Diffraction 268

5.4 Electron Diffraction 301

5.5 Neutron Diffraction 302

5.6 The Reciprocal Lattice 306

5.7 Total scattering and pair distribution function (PDF) analysis 319

5.8 Line broadening of XRD powder patterns, domain (particle) size measurement and strain effects 322

6 Other Characterisation Techniques: Microscopy, Spectroscopy, Thermal Analysis 325

6.1 Diffraction and Microscopic Techniques: What Do They Have in Common? 325

6.2 Optical and Electron Microscopy Techniques 326

6.3 Spectroscopic Techniques 345

6.4 Thermal Analysis (TA) 370

6.5 Strategy to Identify, Analyse and Characterise 'Unknown' Solids 376

7 Phase Diagrams and Their Interpretation 381

7.1 The Phase Rule, the Condensed Phase Rule and Some Definitions 381

7.2 One-Component Systems 386

7.3 Two-Component Condensed Systems 389

7.4 Some Tips and Guidelines for Constructing Binary Phase Diagrams 411

7.5 Ternary Systems 413

7.6 Phase Transitions 439

8 Electrical Properties 469

8.1 Survey of Electrical Properties and Electrical Materials 469

8.2 Metallic Conductivity 471

8.3 Superconductivity 476

8.4 Semi conductivity 492

8.5 Ionic Conductivity 502

8.6 Dielectric Materials 547

8.7 Ferroelectrics 553

8.8 Pyroelectrics 558

8.9 Piezoelectric 558

8.10 Applicati...