Electrochemical Energy Conversion and Storage - Holze, Rudolf

. .

Résumé :

Foreword xi

Preface xiii

1 Processes and Applications of Energy Conversion and Storage 1

2 Electrochemical Processes and Systems 21

2.1 Parasitic Reactions 30

2.2 Self-discharge 30

2.3 Device Deterioration 32

2.3.1 Aging 37

3 Thermodynamics of Electrochemical Systems 39

4 Kinetics of Electrochemical Energy Conversion Processes 55

4.1 Steps of Electrode Reactions and Overpotentials 56

4.2 Transport 56

4.3 Charge Transfer 59

4.4 Overpotentials 59

4.5 Diffusion 62

4.6 Further Overpotentials 63

5 Electrodes and Electrolytes 71

5.1 Recycling 84

6 Experimental Methods 87

6.1 Battery Tester 87

6.2 Current-Potential Measurements 88

6.3 Charge/Discharge Measurements 92

6.4 Battery Charging 100

6.5 Linear Scan and Cyclic Voltammetry 107

6.6 Impedance Measurements 111

6.7 Galvanostatic Intermittent Titration Technique (GITT) 117

6.8 Potentiostatic Intermittent Titration Technique (PITT) 119

6.9 Step Potential Electrochemical Spectroscopy (SPECS) 120

6.10 Electrochemical Quartz Crystal Microbalance (EQCM) 121

6.11 Non-electrochemical Methods 121

6.11.1 Solid-state Nuclear Magnetic Resonance 121

6.11.2 Gas Adsorption Measurements 121

6.11.3 Microscopies 122

6.11.4 Thermal Measurements 122

6.11.5 Modeling 123

7 Primary Systems 127

7.1 Aqueous Systems 129

7.1.1 Zinc-Carbon Battery 129

7.1.2 Alkaline Zn//MnO2 Battery 131

7.1.3 Zn//HgO Battery 134

7.1.4 Zn//AgO Battery 136

7.1.5 Cd//AgO Batteries 138

7.1.6 Mg//MnO2 Batteries 140

7.2 Nonaqueous Systems 141

7.2.1 Primary Lithium Batteries 141

7.2.2 Li//MnO2 144

7.2.3 Li//Bi2O3 145

7.2.4 Li//CuO 146

7.2.5 Li//V2O5, Li//Ag2V4O11, and Li//CSVO 147

7.2.6 Li//CuS 148

7.2.7 Li//FeS2 149

7.2.8 Li//CFx Primary Battery 150

7.2.9 Li//I2 151

7.2.10 Li//SO2 151

7.2.11 Li//SOCl2 153

7.2.12 Li//SO2Cl2 156

7.2.13 Li//Oxyhalide Primary Battery 156

7.3 Metal-Air Systems 157

7.3.1 Aqueous Metal-Air Primary Batteries 157

7.3.2 Nonaqueous Metal-Air Batteries 168

7.4 Reserve Batteries 170

7.4.1 Seawater-activated Batteries 171

7.4.2 High Power Activated Batteries 173

8 Secondary Systems 175

8.1 Aqueous Systems 176

8.1.1 Lead-Acid 176

8.1.2 Lead Grid 181

8.1.3 Ni-based Secondary Batteries 189

8.1.4 Aqueous Rechargeable Lithium Batteries 202

8.1.5 Aqueous Rechargeable Sodium Batteries 206

8.2 Nonaqueous Systems 208

8.2.1 Lithium-Ion Batteries 208

8.2.2 Rechargeable Li//S Batteries 230

8.2.3 Rechargeable Na//S Batteries 233

8.2.4 Rechargeable Li//Se Batteries 234

8.2.5 Rechargeable Mg Batteries 235

8.3 Gel Polymer Electrolyte-based Secondary Batteries 235

8.3.1 Gel Lithium-Ion Batteries 236

8.3.2 Gel-Type Electrolytes for Sodium Batteries 238

8.4 Solid Electrolyte-based Secondary Batteries 238

8.4.1 Solid Lithium-Ion Batteries 239

8.4.2 Rechargeable Solid Lithium Batteries 240

8.5 Rechargeable Metal-Air Batteries 240

8.5.1 Rechargeable Li//Air Batteries 242

8.5.2 Rechargeable Na//Air Batteries 243

8.5.3 Rechargeable Zn//Air Batteries 245

8.6 High-Temperature Systems 246

8.6.1 Sodium-Sulfur Battery 247

8.6.2 Sodium-Nickel Chloride Battery 250

8.6.3 All Liquid Metal Accumalator 254

9 Fuel Cells 257

9.1 The Oxygen Electrode 261

9.2 The ...

Biographie:
Yuping Wu, PhD, is Full Professor at the School of Energy Science and Engineering, Nanjing Tech University in Nanjing, China. He has published more than 360 papers, won many awards such as Distinguished Youth Scientists from NSFC, China, and was selected as one of the Most Influential Minds from Highly Cited Researchers over the World in 2015.

Rudolf Holze, PhD, is Full Professor of Physical Chemistry and Electrochemistry at Chemnitz University of Technology. Germany, at St. Petersburg State University, Russia, Distinguished Professor at Nanjing Tech University, China, and an ordinary member of the Saxon Academy of Sciences. He has authored nine books and more than 450 research articles.
...

Sommaire:
Processes and Applications of Energy Conversion and Storage
Electrochemical Processes and Systems: Classification, Typical Properties and Applications, and Hybrid Types
Thermodynamics of Electrochemical Systems
Kinetics of Electrochemical Energy Conversion Processes
Electrodes and Electrolytes
Experimental Methods
Primary Systems
Secondary Systems
Fuel Cells
Flow Batteries
Supercapacitors
...