Separation Process Principles - D. Keith Roper
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Présentation Separation Process Principles de D. Keith Roper Format Broché
- Livre Technologie
Résumé :
Separation Process Principles with Applications Using Process Simulator, 4th EMEA Edition?is the most comprehensive and up-to-date treatment of the major separation operations in the chemical industry. The 4th edition focuses on using process simulators to design separation processes and prepares readers for professional practice.? ?...
Biographie: Preface to the Fourth Edition v General Nomenclature xiii Dimensions and Units xvii 1. Separation Processes 1 1.0? Instructional Objectives 1 1.1? Industrial Chemical Processes 1 1.2? Basic Separation Techniques 3 1.3? Separations by Phase Creation 4 1.4? Separations by Phase Addition 6 1.5? Separations by Barrier 7 1.6? Separations by an External Field or Gradient 7 1.7? Brief Comparison of Common Separation Operations 8 1.8? Separation Processes, Product Purity, Component Recovery, and Separation Sequences 9 Summary, References, Study Questions, Exercises 2. Thermodynamics of Separation Operations 16 2.0? Instructional Objectives 16 2.1? Phase Equilibria 16 2.2? Ideal-Gas, Ideal-Liquid-Solution Model 20 2.3? Graphical Representation of Thermodynamic Properties 21 2.4? Nonideal Thermodynamic Property Models 23 2.5? P-v-T Equation-of-State (EOS) Models 23 2.6? Highly Nonideal Liquid Solutions 27 2.7? Gibbs Excess Free-Energy (gE) Models 29 2.8? Predictive Models 34 2.9? Electrolyte Solution Models 36 2.10? Polymer Solution Models 36 2.11? K-Value Methods in Process Simulators 36 2.12? Exergy and Second-Law Analysis 37 Nomenclature, Summary, References, Study Questions, Exercises 3. Mass Transfer and Diffusion 46 3.0? Instructional Objectives 46 3.1? Steady-State, Ordinary Molecular Diffusion 47 3.2? Diffusion Coefficients (Diffusivities) 51 3.3? Steady-State and Unsteady-State Mass Transfer Through Stationary Media 58 3.4? Mass Transfer in Laminar Flow 60 3.5? Mass Transfer in Turbulent Flow 68 3.6? Models for Mass Transfer in Fluids with a Fluid-Fluid Interface 73 3.7? Two-Film Theory and Overall Mass-Transfer Coefficients 76 Nomenclature, Summary, References, Study Questions, Exercises 4. Single Equilibrium Stages and Flash Calculations 87 4.0? Instructional Objectives 87 4.1? Gibbs' Phase Rule and Degrees of Freedom 88 4.2? Binary Vapor-Liquid Systems at Equilibrium 89 4.3? Equilibrium Two-Phase Flash Calculations 93 4.4? Ternary Liquid-Liquid Systems at Equilibrium 97 4.5? Multicomponent Liquid-Liquid Systems 101 4.6? Liquid-Solid Systems 102 4.7? Gas-Liquid Systems 104 4.8? Gas-Solid Systems 105 4.9? Three-Phase Equilibrium Systems 107 Nomenclature, Summary, References, Study Questions, Exercises 5. Multistage Cascades and Hybrid Systems 118 5.0? Instructional Objectives 118 5.1? Cascade Configurations 118 5.2? Single-Section Liquid-Liquid Extraction Cascades 119 5.3? Two-Section Distillation Cascades 121 5.4? Membrane Cascades 123 5.5? Hybrid Systems 125 5.6? Degrees of Freedom and Specifications for Cascades 125 Nomenclature, Summary, References, Study Questions, Exercises 6. Absorption and Stripping 137 6.0? Instructional Objectives 137 6.1? Equipment for Vapor-Liquid Separations 138 6.2? General Design Considerations 143 6.3? Graphical Method for Trayed Towers 144 6.4? Kremser Group Method for Multicomponent Absorption and Stripping 148 6.5? Stage Efficiency and Column Height for Trayed Columns 154 6.6? Flooding, Column Diameter, and Tray Layout for Trayed Columns 161 6.7? Rate-Based Method for Packed Columns 164 6.8? Packed-Column Liquid Holdup, Diameter, Flooding, Pressure Drop, and Mass-Transfer Efficiency 169 6.9? Reactive (Chemical) Absorption 180 Nomenclatu...
About the Authors iii
Sommaire: Preface to the Fourth Edition v General Nomenclature xiii Dimensions and Units xvii 1. Separation Processes 1 1.0? Instructional Objectives 1 1.1? Industrial Chemical Processes 1 1.2? Basic Separation Techniques 3 1.3? Separations by Phase Creation 4 1.4? Separations by Phase Addition 6 1.5? Separations by Barrier 7 1.6? Separations by an External Field or Gradient 7 1.7? Brief Comparison of Common Separation Operations 8 1.8? Separation Processes, Product Purity, Component Recovery, and Separation Sequences 9 Summary, References, Study Questions, Exercises 2. Thermodynamics of Separation Operations 16 2.0? Instructional Objectives 16 2.1? Phase Equilibria 16 2.2? Ideal-Gas, Ideal-Liquid-Solution Model 20 2.3? Graphical Representation of Thermodynamic Properties 21 2.4? Nonideal Thermodynamic Property Models 23 2.5? P-v-T Equation-of-State (EOS) Models 23 2.6? Highly Nonideal Liquid Solutions 27 2.7? Gibbs Excess Free-Energy (gE) Models 29 2.8? Predictive Models 34 2.9? Electrolyte Solution Models 36 2.10? Polymer Solution Models 36 2.11? K-Value Methods in Process Simulators 36 2.12? Exergy and Second-Law Analysis 37 Nomenclature, Summary, References, Study Questions, Exercises 3. Mass Transfer and Diffusion 46 3.0? Instructional Objectives 46 3.1? Steady-State, Ordinary Molecular Diffusion 47 3.2? Diffusion Coefficients (Diffusivities) 51 3.3? Steady-State and Unsteady-State Mass Transfer Through Stationary Media 58 3.4? Mass Transfer in Laminar Flow 60 3.5? Mass Transfer in Turbulent Flow 68 3.6? Models for Mass Transfer in Fluids with a Fluid-Fluid Interface 73 3.7? Two-Film Theory and Overall Mass-Transfer Coefficients 76 Nomenclature, Summary, References, Study Questions, Exercises 4. Single Equilibrium Stages and Flash Calculations 87 4.0? Instructional Objectives 87 4.1? Gibbs' Phase Rule and Degrees of Freedom 88 4.2? Binary Vapor-Liquid Systems at Equilibrium 89 4.3? Equilibrium Two-Phase Flash Calculations 93 4.4? Ternary Liquid-Liquid Systems at Equilibrium 97 4.5? Multicomponent Liquid-Liquid Systems 101 4.6? Liquid-Solid Systems 102 4.7? Gas-Liquid Systems 104 4.8? Gas-Solid Systems 105 4.9? Three-Phase Equilibrium Systems 107 Nomenclature, Summary, References, Study Questions, Exercises 5. Multistage Cascades and Hybrid Systems 118 5.0? Instructional Objectives 118 5.1? Cascade Configurations 118 5.2? Single-Section Liquid-Liquid Extraction Cascades 119 5.3? Two-Section Distillation Cascades 121 5.4? Membrane Cascades 123 5.5? Hybrid Systems 125 5.6? Degrees of Freedom and Specifications for Cascades 125 Nomenclature, Summary, References, Study Questions, Exercises 6. Absorption and Stripping 137 6.0? Instructional Objectives 137 6.1? Equipment for Vapor-Liquid Separations 138 6.2? General Design Considerations 143 6.3? Graphical Method for Trayed Towers 144 6.4? Kremser Group Method for Multicomponent Absorption and Stripping 148 6.5? Stage Efficiency and Column Height for Trayed Columns 154 6.6? Flooding, Column Diameter, and Tray Layout for Trayed Columns 161 6.7? Rate-Based Method for Packed Columns 164 6.8? Packed-Column Liquid Holdup, Diameter, Flooding, Pressure Drop, and Mass-Transfer Efficiency 169 6.9? Reactive (Chemical) Absorption 180 Nomenclatu...
About the Authors iii
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