Liquid-Phase Reaction Rate Constants - Denisov, E. T.

. .

Sommaire:
one - Reactions of Molecules.- I. Monomolecular reactions.- 1. Methods for Measuring Rate Constants of Monomolecular Reactions.- 2. Rate Constants for Decomposition of Peroxide Compounds.- 3. Decomposition of Azo Compounds.- 4. Decomposition at C - C, N-N, N-C,N-O, and C-Metal Bonds.- 5. Decomposition of Iodobenzene Dichloride.- 6. Correlation Equations.- 7. Effect of Pressure and Solvent on Monomolecular Reactions.- II. Bimolecular and Trimolecular Reactions.- 1. Methods for Measuring Rate Constants of Bimoleeular Reactions.- 2. Diels-Alder Reaction.- 3. Bimolecular Reactions with Peroxide Participation.- 4. Oxidation-Reduction Reactions with Participation of CIO2, O2, and CI2.- 5. Reactions with Rupture of Metal-Carbon Bond.- 6. Trimolecular Reactions.- III. The cage effect.- 1. Questions of Theory.- 2. Methods for Measuring Initiator Efficiency.- 3. Initiator Efficiency.- Literature Cited (Part One).- Two - Reactions of free Atoms and Radicals.- IV. Methods for Measuring Rate Constants of Radical Reactions.- 1. Measurement of Relative Rate Constants of Radical Reactions.- 2. Measurement of Absolute Rate Constants of Reactions of Atoms and Radicals.- V. Isomerization and Decomposition of Free Radicals.- 1. Isomerization of Free Radicals.- 2. Decomposition of Free Radicals.- VI. Radical Substitution Reactions.- 1. Reactions of Atoms.- 2. Reactions of Radicals Having Free Valence on Oxygen.- 3. Reactions of Radicals Having Free Valence on Carbon.- 4. Chain Transfer in Radical Polymerization.- 5. Reactions of Radicals Having Free Valence on Nitrogen.- 6. Correlation Equations for Radical Substitution Reactions.- VII. Addition Reactions of Atoms and Radicals.- 1. Addition of Atoms and Radicals to Molecular Oxygen.- 2. Addition at C = C Bond.- 3. Addition to Aromatic Compounds.- 4. Addition to Quinones, Carbonyl Compounds, Nitriles, and Nitro Compounds.- VIII. Recombination and Disproportionate of Free Atoms and Radicals.- 1. Recombination of Atoms.- 2. Disproportionation and Recombination of Alkyl and RO? Radicals.- 3. Reactions between Peroxy Radicals.- 4. Reactions of Radicals Having Free Valence on Nitrogen or Tin.- 5. Reactions between Free Radicals of Different Types.- IX. Effect of Solvent on Free Radical Reactions.- 1. Solvent Viscosity.- 2. Internal Pressure of Liquid.- 3. Nonspecific Solvation.- 4. Hydrogen Bond between Molecules.- 5. Radical Hydrogen Bond.- 6. Formation of ? -Complexes.- Literature Cited (Part Two).- Three - Ionic Homolytic Reactions.- X. Oxidation-Reduction Reactions of Ions With Molecules.- Oxidation of Organic Compounds by Variable-Valence Metal Ions.- Reaction of Variable-Valence Metal Ions with Oxygen, Peroxides, and Quinones.- XI. Reactions of Atoms and Radicals with Ions.- 1. Reactions of Hydrogen Atom.- 2. Reactions of Free Radicals.- XII. Reactions of Ion-Radicals and Solvated Electrons.- 1. Reactions of Ion-Radicals.- 2. Solvated Electron.- XIII. Ionic Oxidation-Reduction Reactions.- 1. Methods for Measuring Reaction Rates for Electron Transfer from Ion to Ion.- 2. Electron Exchange Reactions.- 3. Oxidation-Reduction Reactions between Ions.- Literature Cited (Part Three).