Physical Methods for Inorganic Biochemistry - Hendrickson, Wayne A.

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Sommaire:
1. Introduction.- 1.1 Physical Methods.- 1.2 Probable Future Trends in Physical Instrumentation.- References.- 2. Nuclear Magnetic Resonance (Nmr).- 2.1 The Phenomenon.- 2.2 Multinuclear Nmr.- 2.3 Nmr Phenomena Related to Molecular Structure.- 2.4 Instrument Characteristics.- 2.5 Sample Manipulation (Two-Way Communication).- 2.6 Biological Considerations.- References.- Appendix A: Correlation Nmr.- Appendix B: Mathematical Symbols Used in Chapter 2.- 3. Nuclear Quadrupole Resonance (Nqr).- 3.1 Properties of Nqr.- 3.2 Relationship to M?ssbauer, Esr, and Nmr Spectroscopy.- 3.3 Instrumentation.- 3.4 Applications.- References.- 4. M?ssbauer Spectroscopy.- 4.1 Instrumentation.- 4.2 Conversion Electron Detection.- 4.3 Sample Considerations.- 4.4 M?ssbauer Effect and the Chemical Environment.- 4.5 Biological Applications of 57Fe.- 4.6 M?ssbauer Isotopes Other than 57Fe.- 4.7 M?ssbauer Emission Spectra.- 4.8 Bragg Scattering Effects.- References.- 5. Electron Spin Resonance (Esr).- 5.1 Introduction.- 5.2 Theory.- 5.3 Esr Instrumentation.- 5.4 Applications.- References.- 6. X-ray Diffraction Methods for the Analysis of Metalloproteins.- 6.1 Introduction.- 6.2 Theoretical Basis.- 6.3 Experimental Procedures.- 6.4 Structural Analysis.- 6.5 Applications.- References.- 7. Electron Energy Levels: Electron Spectroscopy and Related Methods.- 7.1 Electron Spectroscopy for Chemical Analysis (ESCA) and Ultraviolet Photoelectron Spectroscopy (UPS).- 7.2 Auger (Secondary Electron) Spectroscopy.- References.- 8. Laser Applications: Resonance Raman (RR) Spectroscopy and Related Methods.- 8.1 Perspective.- 8.2 Resonance Raman (RR) Spectroscopy.- 8.3 Sample Considerations.- 8.4 Symmetry and the Intensity of Vibrational Absorptions.- 8.5 Vibrational Energy Levels.- 8.6 Applications.- 8.7Newer Methods Which Minimize Fluorescence Interference.- References.- 9. Circular Dichroism (CD) and Magnetic Circular Dichroism (MCD).- 9.1 The Relationship between ORD, CD, MORD, and MCD.- 9.2 Sample Considerations.- 9.3 Effects Observed in MCD Spectra.- 9.4 Biochemical Applications.- References.- 10. Kinetic Methods.- 10.1 Introduction.- 10.2 Methods.- 10.3 Applications.- References.- 11. Bioinorganic Topochemistry: Microprobe Methods of Analysis.- 11.1 Electron Probe Microanalysis.- 11.2 Ion, Laser, and Proton Microprobe Analysis of Elements.- References.- 12. Neutron Activation Analysis.- 12.1 Introduction.- 12.2 Applications and Examples of Neutron Activation.- References.