Principles of Combustion - Allan T. Kirkpatrick

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Résumé :

About the Authors xiii

Preface xv

Acknowledgments xvii

About the Companion Website xix

1 Introduction to Combustion 1

1.1 Introduction 1

1.2 Combustion Applications 2

1.3 Organization of Text 2

1.4 Solution Methods for Combustion Problems 3

1.5 Fuels Background 4

1.6 Hydrocarbon Fuel Chemistry 5

1.7 Gaseous and Liquid Fuels for Combustion Engines 9

1.8 Fuels for Rocket Engines 20

1.9 Solid Fuels 21

1.10 Additional Reading 23

References 24

Homework Problems 24

2 Chemical Thermodynamics 27

2.1 Introduction 27

2.2 Properties of Gas Mixtures 28

2.3 Liquid-Vapor-Gas Mixtures 35

2.4 Standard Enthalpies of Formation 40

2.5 Relationship Between Bond Energy and Enthalpy of Formation 41

2.6 Fugacity and Real-Gas Equations of State 44

2.7 Conservation of Mass 48

2.8 The First Law of Thermodynamics 50

2.9 The Second Law of Thermodynamics 51

2.10 Stoichiometric Chemical Reactions 55

2.11 Mixture Fraction f 58

2.12 First Law Analysis of Combustion 61

2.13 Second Law Analysis of Cyclic Engines 67

2.14 Equilibrium Constant K p 71

2.15 Chemical Equilibrium Using Lagrange Multipliers 74

2.16 Chemical Equilibrium Using Equilibrium Constants 78

2.17 Thermodynamic Properties of Combustion Products 82

References 84

Homework Problems 84

3 Chemical Kinetics 87

3.1 Introduction 87

3.2 Rates of Reaction and Their Functional Dependence 87

3.3 One-Step Chemical Reactions of Various Orders 101

3.4 Chain Reactions 110

3.5 Chain-Branching Reactions and Explosions 111

3.6 Pressure Dependence of Rate Coefficients 115

3.7 Surface Reactions 117

3.8 Surface Reaction Kinetics 122

3.9 Experimental Methods for Measurement of Gas-Phase Reaction Rates 128

3.10 Experimental Methods to Study Surface Reactions 136

References 138

Homework Problems 140

4 Reaction Mechanisms 143

4.1 Introduction 143

4.2 Multiple Reactions 143

4.3 Steady-State Approximation 144

4.4 Partial Equilibrium 144

4.5 Hydrogen H 2 Reaction Mechanisms 145

4.6 Ammonia NH 3 Reaction Mechanisms 148

4.7 Hydrocarbon Reaction Mechanisms 149

4.8 Additional Hydrocarbon Reaction Mechanisms 156

4.9 Reduced Mechanism of Hydrocarbon Combustion 164

4.10 Chemical Mechanism Reduction 169

4.11 Sensitivity Analysis 171

4.12 Reaction Flow Analysis 178

4.13 Computational Singular Perturbation (CSP) 181

References 183

Homework Problems 185

5 Transport Processes 189

5.1 Introduction 189

5.2 Definitions of Concentrations, Velocities, and Mass Fluxes 190

5.3 Fick's Law of Diffusion 192

5.4 Dimensionless Ratios of Transport Coefficients 193

5.5 Theory of Mass Diffusion in Gases at Low Density 193

5.6 Continuity Equation and Species Mass Conservation Equations 195

5.7 Conservation of Momentum 198

5.8 Conservation of Energy 207

5.9 Physical Derivation of the Multicomponent Diffusion Equation 210

5.10 Shvab-Zel'dovich Formulation 214

5.11 Boundary Conditions at an Interface 218

5.12 Turbulent Flow Fields 227

5.13 Turbulent Length, Velocity, and Time Scales 230

5.14 Reynolds and Favre Averaging 235

5.15 Turbulence Modeling 237

5.16 Probability Density Function (PDF) Models 242

5.17 Further Reading 247

References 247

Homework Problems 247

6 Premixed Flames 251

6.1 Introduction 251

6.2...

Biographie:

About the Authors xiii

Preface xv

Acknowledgments xvii

About the Companion Website xix

1 Introduction to Combustion 1

1.1 Introduction 1

1.2 Combustion Applications 2

1.3 Organization of Text 2

1.4 Solution Methods for Combustion Problems 3

1.5 Fuels Background 4

1.6 Hydrocarbon Fuel Chemistry 5

1.7 Gaseous and Liquid Fuels for Combustion Engines 9

1.8 Fuels for Rocket Engines 20

1.9 Solid Fuels 21

1.10 Additional Reading 23

References 24

Homework Problems 24

2 Chemical Thermodynamics 27

2.1 Introduction 27

2.2 Properties of Gas Mixtures 28

2.3 Liquid-Vapor-Gas Mixtures 35

2.4 Standard Enthalpies of Formation 40

2.5 Relationship Between Bond Energy and Enthalpy of Formation 41

2.6 Fugacity and Real-Gas Equations of State 44

2.7 Conservation of Mass 48

2.8 The First Law of Thermodynamics 50

2.9 The Second Law of Thermodynamics 51

2.10 Stoichiometric Chemical Reactions 55

2.11 Mixture Fraction f 58

2.12 First Law Analysis of Combustion 61

2.13 Second Law Analysis of Cyclic Engines 67

2.14 Equilibrium Constant K p 71

2.15 Chemical Equilibrium Using Lagrange Multipliers 74

2.16 Chemical Equilibrium Using Equilibrium Constants 78

2.17 Thermodynamic Properties of Combustion Products 82

References 84

Homework Problems 84

3 Chemical Kinetics 87

3.1 Introduction 87

3.2 Rates of Reaction and Their Functional Dependence 87

3.3 One-Step Chemical Reactions of Various Orders 101

3.4 Chain Reactions 110

3.5 Chain-Branching Reactions and Explosions 111

3.6 Pressure Dependence of Rate Coefficients 115

3.7 Surface Reactions 117

3.8 Surface Reaction Kinetics 122

3.9 Experimental Methods for Measurement of Gas-Phase Reaction Rates 128

3.10 Experimental Methods to Study Surface Reactions 136

References 138

Homework Problems 140

4 Reaction Mechanisms 143

4.1 Introduction 143

4.2 Multiple Reactions 143

4.3 Steady-State Approximation 144

4.4 Partial Equilibrium 144

4.5 Hydrogen H 2 Reaction Mechanisms 145

4.6 Ammonia NH 3 Reaction Mechanisms 148

4.7 Hydrocarbon Reaction Mechanisms 149

4.8 Additional Hydrocarbon Reaction Mechanisms 156

4.9 Reduced Mechanism of Hydrocarbon Combustion 164

4.10 Chemical Mechanism Reduction 169

4.11 Sensitivity Analysis 171

4.12 Reaction Flow Analysis 178

4.13 Computational Singular Perturbation (CSP) 181

References 183

Homework Problems 185

5 Transport Processes 189

5.1 Introduction 189

5.2 Definitions of Concentrations, Velocities, and Mass Fluxes 190

5.3 Fick's Law of Diffusion 192

5.4 Dimensionless Ratios of Transport Coefficients 193

5.5 Theory of Mass Diffusion in Gases at Low Density 193

5.6 Continuity Equation and Species Mass Conservation Equations 195

5.7 Conservation of Momentum 198

5.8 Conservation of Energy 207

5.9 Physical Derivation of the Multicomponent Diffusion Equation 210

5.10 Shvab-Zel'dovich Formulation 214

5.11 Boundary Conditions at an Interface 218

5.12 Turbulent Flow Fields 227

5.13 Turbulent Length, Velocity, and Time Scales 230

5.14 Reynolds and Favre Averaging 235

5.15 Turbulence Modeling 237

5.16 Probability Density Function (PDF) Models 242

5.17 Further Reading 247

References 247

Homework Problems 247

6 Premixed Flames 251

6.1 Introduction 251

6.2...

Sommaire:

Allan T. Kirkpatrick is an Emeritus Professor of Mechanical Engineering at Colorado State University, where he developed and taught a wide variety of courses in the thermal science areas. As an internationally recognized authority in the applied thermal-fluid sciences, Dr. Kirkpatrick has published four books and more than 100 publications on internal combustion engines, emissions, combustion instability, fluid jets, and engineering education.

Kenneth K. Kuo was a Distinguished Professor of Mechanical Engineering and Director of the High Pressure Combustion Laboratory (HPCL) in the Department of Mechanical and Nuclear Engineering at The Pennsylvania State University. The author of three books, Professor Kuo was widely recognized as a leading researcher and expert in propulsion-related combustion....