Phthalocyanine-Based Functional Polymeric Materials - Jiang, Jianzhuang

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Résumé :

A carefully curated collection of resources covering the concepts, perspectives, and applications of phthalocyanine chemistry

In Phthalocyanine-Based Functional Polymeric Materials: Design, Synthesis, and Applications, a team of distinguished researchers delivers a comprehensive discussion of phthalocyanine-involving hybrids, molecular cages, coordination polymers, covalent organic frameworks, and organic polymers. The book also explains a diverse array of the applications of these novel materials in chemical sensors, organic catalysts, electrocatalysis, photocatalysis, energy storage, and more.

The authors have included material designed to help you improve the design of monomers to synthesize polymers with desired functionalities. A valuable reference in the development of phthalocyanine chemistry, readers will also find:

• A thorough introduction to phthalocyanine-based polymers and their uses in sensors, catalysis, energy storage, and other applications
• Comprehensive explorations of the extended molecular systems of phthalocyanines, filling the gap between monomeric phthalocyanine compounds and polymers
• Practical discussions of a variety of phthalocyanine-based polymer systems, their potential applications, and major design and synthesis challenges
• Complete treatments of these novel materials appropriate for readers in academia and industry

Perfect for polymer, organic, inorganic, catalytic, complex, and structural chemists, Phthalocyanine-Based Functional Polymeric Materials will also benefit materials scientists and chemists working in industry....

Biographie:

Jianzhuang Jiang, PhD, is Professor at the University of Science and Technology Beijing, China. His research is focused on single-molecule magnets, organic field-effect transistors, linear and nonlinear optical materials, and new energy materials.

Hailong Wang, PhD, is Professor at the University of Science and Technology Beijing, China. His research is focused on porous molecular crystals and tetrapyrrole-based crystalline materials.

Kang Wang, PhD, is Professor at the University of Science and Technology Beijing, China. His research is focused on the synthesis of conjugate extended tetrapyrrole and tetrapyrrole-fused oligomer skeletons, as well as the synthesis and application of tetrapyrrole-based conjugated mesoporous organic frameworks....

Sommaire:

1 A Journey from Molecular Phthalocyanines to Polymeric Materials 1

1.1 Introduction 1

1.2 Monophthalocyanines 4

1.2.1 Tetra-Substituted Monophthalocyanines 6

1.2.2 Octa-Substituted Monophthalocyanines 7

1.3 Phthalocyanine-Based Oligomers 9

1.3.1 Sandwich-Type Phthalocyanine-Based Complexes 9

1.3.2 ?-Oxo-Linked Phthalocyanine-Based Oligomers 12

1.3.3 Phthalocyanine-Based Supramolecular Oligomers 13

1.3.4 Phthalocyanine-Based Covalent-Bonded Oligomers 16

1.3.4.1 Phthalocyanine-Based Fused Oligomers 16

1.3.4.2 Phthalocyanine-Based Covalent-Linked Oligomers 19

1.3.5 Cofacial and Cage-Like Phthalocyanine-Based Compounds 20

1.4 Phthalocyanine-Based Polymeric Materials 23

1.4.1 Phthalocyanine-Based Porous Molecular Crystals 23

1.4.2 Phthalocyanine-Based Coordination Polymers 25

1.4.3 Phthalocyanine-Based Organic Polymers 29

1.4.3.1 Amorphous Phthalocyanine-Based Organic Polymers 29

1.4.3.2 Phthalocyanine-Based COFs 33

1.5 Porous Polymeric Materials for Functional Applications 36

1.5.1 Phthalocyanine-Based Polymeric Materials for Chemical Sensors 36

1.5.2 Phthalocyanine-Based Polymeric Materials for Electrocatalysis 37

1.5.3 Phthalocyanine-Based Polymeric Materials for Photocatalysts 40

1.5.4 Phthalocyanine-Based Polymeric Materials for Energy Storage 42

1.6 Conclusion 43

Abbreviations 43

References 44

2 Phthalocyanine-Based Cages 55

2.1 Introduction 55

2.1.1 Metal-Organic Cages 55

2.1.2 Porous Organic Cages 56

2.2 Phthalocyanine-Based Cages 57

2.2.1 Pc-Based MOCs 57

2.2.2 Pc-Based POCs 58

2.2.3 Subphthalocyanine-Based Cages 64

2.2.4 Other Phthalocyanine-Based Molecule Cages 65

2.3 Electrochemical Properties of Pc-Based Cages 73

2.4 Photophysical Properties of Pc-Based Cage 77

2.5 Gas-Sensing Properties of Pc-Based Cage 80

2.6 Host-Guest Properties of Pc-Based Molecular Cages 80

2.7 Conclusion 82

Abbreviations 84

References 84

3 Phthalocyanine-Based Coordination Polymers 89

3.1 Introduction 89

3.2 Synthesis of Pc-Based MOFs 90

3.2.1 The First Pc-Based Porous Coordination Polymers 91

3.2.2 MOFs Based on Octahydroxy-Pcs 92

3.2.3 MOFs Based on Amino-Pcs 98

3.2.4 MOFs Based on Carboxyl-Substituted Pcs 103

3.3 Electrochemical Properties of Pc-Based MOFs 106

3.4 The Nanocomposite of Pcs with Different MOFs Systems 113

3.5 The Axial Polymer of Pcs 125

3.6 The Polymers Based on the Co-Assembly of Pcs with Cyclodextrin 128

3.7 The Nanocomposite of Pcs with MOFs and COFs 130

3.8 Conclusion 132

Abbreviations 132

References 133

4 Porous Phthalocyanine-Based Organic Polymers 137

4.1 Introduction 137

4.2 Pc-Based CMPs 139

4.2.1 Imine-Linked Pc-Based CMPs 140

4.2.2 Ethynyl-Linked Pc-Based CMPs 144

4.2.3 Other Mode-Linked Pc-Based CMPs 146

4.3 Pc-Based COFs 148

4.3.1 Octahydroxyphthalocyanine-Derived COFs 150

4.3.2 Octaaminophthalocyanine-Derived COFs 157

4.3.3 Octacarboxyphthalocyanine-Derived COFs 164

4.3.4 Hexadecafluorophthalocyanine-Derived COFs 169

4.4 Polyphthalocyanines 172

4.4.1 Amorphous Polyphthalocyanines 173

4.4.2 Crystalline Polyphthalocyanines 180

4.5 Conclusion 184

Abbreviations 185

References 188

5 Sensors Based on Phthalocyanine Polymers and Covalent Organic Frameworks 193

5.1 Introduction 193

5.2 Basic Parameters for Sensors 194

5.3 Pc-Based NO2 /NH3 /NO2? ?Sens...