Wearable Solar Cells - Sun, Hao

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Résumé :

About the Authors ix

Preface xi

1 Introduction 1

1.1 Development of Wearable Solar Cells 1

1.2 Characteristics of Fiber-Shaped Solar Cells 2

1.3 Functionalization and Integration 2

1.4 Applications of Wearable Solar Cells 3

References 4

2 Working Mechanisms of Solar Cells 7

2.1 Introduction 7

2.2 Working Mechanism and Efficiency Limitation for Solar Cells 8

2.2.1 Detailed Balance Limitation 12

2.2.2 Drift-Diffusion Model 14

2.2.3 Equivalent Circuit Model 15

2.3 Working Mechanism of Dye-Sensitized Solar Cells 16

2.4 Working Mechanism of Polymer Solar Cells 18

2.5 Working Mechanism of Perovskite Solar Cells 19

2.6 Comparison of Solar Cells for Flexible and Wearable Application 22

2.7 Conclusions 24

References 25

3 Flexible Film Solar Cells 31

3.1 Overview of Flexible Film Solar Cells 31

3.2 Flexible Transparent Conductive Electrodes 31

3.2.1 Metal Oxides 32

3.2.2 Conductive Polymers 33

3.2.3 Carbon Nanomaterials 34

3.2.3.1 Graphene 34

3.2.3.2 Carbon Nanotube 37

3.3 Fabrication Techniques of Flexible Film Solar Cells 39

3.3.1 Spin Coating 40

3.3.2 Blade Coating 41

3.3.3 Slot-Die Coating 43

3.3.4 Screen Printing 43

3.3.5 Roll-to-Roll System 45

3.4 Flexible Organic Solar Cells 46

3.5 Flexible Dye-Sensitized Solar Cells 50

3.6 Flexible Perovskite Solar Cells 53

3.7 Summary and Perspective 56

References 58

4 Flexible Fiber Electrodes 67

4.1 Introduction 67

4.2 Metal Wires 68

4.2.1 Titanium 68

4.2.2 Stainless Steel 70

4.2.3 Other Metals 70

4.3 Polymer Fibers 71

4.4 Carbon-Based Fiber 73

4.4.1 Carbon Fiber 73

4.4.2 Carbon Nanotube Fiber 75

4.4.3 Graphene Fiber 83

4.5 Functional Fibers 87

4.6 Summary and Perspectives 88

References 89

5 Fiber-Shaped Dye-Sensitized Solar Cells 95

5.1 Introduction 95

5.2 Twisting Structure 97

5.2.1 Photoanode 97

5.2.2 Counter Electrode 101

5.2.3 Electrolyte 104

5.3 Coaxial Structure 105

5.4 Functionalization and Integration 106

5.4.1 Functional Fiber-Shaped DSSCs 107

5.4.2 Integrated Fiber-Shaped DSSCs 109

5.5 Summary and Prospects 114

References 115

6 Fiber Polymer Solar Cells 121

6.1 Overview of Polymer Solar Cells 121

6.2 Overview of Fiber-Shaped Polymer Solar Cells 123

6.2.1 Fiber-Shaped Polymer Solar Cells with Twisting Structure 123

6.2.2 Fiber Polymer Solar Cells with a Coaxial Structure 127

6.3 Polymer Solar Cell Textiles 129

6.4 Summary and Perspective 130

References 132

7 Fiber Perovskite Solar Cells 135

7.1 Introduction 135

7.2 Perovskite Photoactive Materials and Solar Cells 136

7.3 Deposition of Perovskite Layer on Fiber/Wire Surfaces 139

7.3.1 Perovskite Formation Strategies 139

7.3.2 Dip-Coating Process 142

7.3.3 Cathodic Electrodeposition 145

7.3.4 Thermal Evaporation 145

7.3.5 Electrode-Spinning 146

7.4 Charge Transport Layers for Fiber Perovskite Solar Cells 147

7.5 Electrode Materials for Fiber Perovskite Solar Cells 149

7.6 Stretchable and Wearable Fiber Perovskite Solar Cells 149

7.7 Summary and Perspectives: Challenges for Fiber Perovskite Solar Cells 151

References 153

8 Fiber-Shaped Integrated Device 159

8.1 Overview of Integrated Device Based on Solar Cells 159

8.2 Overview of Fiber-Integrated Device Based on Solar C...

Biographie:
Hao Sun is currently Associate Professor at Shanghai Jiao Tong University. He received his Ph. D. degree in Polymer Chemistry and Physics at Fudan University, China in 2017, and worked at Stanford University as a Postdoc Fellow during 2017-2020. His research centers on multifunction and integration of fiber-shaped energy harvesting and storage devices, and safe and high-performance battery systems. He has received scientific awards including Materials Research Society Graduate Student Gold Award and Geneva International Exhibition of Inventions Silver Medal.
Zhibin Yang is Associate Professor in School of Chemistry and Chemical Engineering at Shanghai Jiao Tong University. He received bachelor's degree from East China University of Science and Technology in 2009 and Ph.D. from Fudan University in 2014. Between 2014-2019, he conducted his postdoctoral research in University of Washington and The University of North Carolina at Chapel Hill, successively. His current research focuses on perovskite solar cells and wearable electronics.
Longbin Qiu is Assistant Professor at Southern University of Science and Technology, China. He received his bachelor?s degree (2011) and Ph.D. (2016) from Sun Yat-sen University and Fudan University, respectively. He conducted his postdoctoral research in Energy Materials and Surface Sciences Unit at Okinawa Institute of Science and Technology Graduate University in Japan during 2016-2020. His current interests focus on the scalable and stable perovskite solar modules, as well as flexible and wearable electronics.
Professor Huisheng Peng received his BEng in Polymer Materials from Donghua University in China in 1999, MSc in Polymer Science from Fudan University in 2003 and PhD in Chemical & Biomolecular Engineering from Tulane University in USA in 2006. He worked at Los Alamos National Laboratory, US Department of Energy, from 2006 to 2008. He has been appointed as Professor in Department of Macromolecular Science and Laboratory of Advanced Materials at Fudan University since 2008 and become University Professor since 2019. He is recognized as a pioneer of fiber electronics, an interface direction of chemistry, physics, biology, energy and engineering. He and co-workers have invented a new family of soft fiber energy harvesting devices including perovskite solar cells and fluidic generators, fiber energy storage devices including lithium-ion batteries, lithium-sulfur batteries and metal-air batteries, fiber light-emitting devices, fiber chips and fiber biosensors. Professor Peng has published over 290 peer-reviewed papers and 4 books. He obtains 74 issued patents with 34 royally transferred to the industry for commercialization. He has received over 30 awards including National Natural Science Award of China. He also serves as editor and editorial board member for over 10 journals such as Advanced Functional Materials.
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Sommaire:
Preface
Chapter 1. Introduction
Chapter 2. Working Mechanisms of Solar Cells
Chapter 3. Flexible Film Solar Cells
Chapter 4. Flexible Fiber Electrodes
Chapter 5 Fiber-shaped Dye-sensitized Solar Cells
Chapter 6. Fiber Polymer Solar Cells
Chapter 7. Fiber Perovskite Solar Cells
Chapter 8. Fiber-Shaped Integrated Device
Chapter 9. Novel Interfaces in Wearable Solar Cells
Chapter 10 Textile Solar Cells
Chapter 11. Summary and Outlook
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